The following Aldermen served as Mayor of Enfield Municipal Council from 1889 to 1949. * denotes service as Member of NSW Parliament.
| Date | Name |
|---|---|
| 1889-1891 | James Eve* |
| 1891-1892 | Thomas Hodson |
| 1892-1893 | Herman Henry Groth |
| 1893-1894 | George Westbrook |
| 1894 | Kenneth Matheson |
| 1894-1896 | Henry George Lipscomb |
| 1896-1897 | George Washington Eaton |
| 1897-1903 | Thomas Hodson |
| 1903-1904 | Henry Chesterton Pilcher |
| 1904-1907 | James Mackay |
| 1908-1909 | Albert Edward Weil |
| 1909-1910 | James Mackay |
| 1910-1914 | George Barnett Phillips |
| 1914-1915 | Frederick Williams |
| 1915-1917 | Ebenezer Ford |
| 1917-1919 | Frederick Williams |
| 1919-1920 | Adrian Burgess |
| 1920-1929 | Ebenezer Ford |
| 1929-1935 | Stanley Allan Lloyd* |
| 1935-1937 | Reuben Herbert Jenner |
| 1937-1938 | William Ernest Flockhart |
| 1938-1939 | James Mooney |
| 1939-1940 | James William Parkes |
| 1941-1946 | Thomas Edward Cooke |
| 1946-1947 | William John Sky |
| 1947-1948 | Thomas Cooke |
James Eve was Member of the Legislative Assembly (Electorate of Canterbury) from September 1891 to June 1894.
Stanley Lloyd was Member of the Legislative Assembly (Electorate of Concord) from 1932-1941.
